Here's a list of Heroes with High Critical rates, available from the game Marvel: Avengers Alliance. Refer here to learn the best, top or most used Heroes around the game. The list below is based on gathered observations and suggestions from players.
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Heroes with high critical rates usually have a high accuracy stat or an ability that would increase their critical chance or accuracy stat. Some heroes also have a debuff attribute that targets enemies making the next attack against that target to become a guaranteed crit.
Note: To further increase your Heroes' critical chances, increase their accuracy stat.
Daredevil (48 CP)
Daredevil is one of the most favored hero when it comes to critical rates and dodge because of his "Radar Sense". It greatly boosts Daredevil's accuracy and evasion stats with a bonus counter attack whenever he is attacked with single-target attacks! You don't even need to wait for another turn to utilize it!
War Machine (48 CP)
War Machine's "Blade Punch" has a very high base critical rate that can also ignore any defenses! Automatically unlocks after recruiting him.
Wolverine (90 CP)
Wolverine's "Adamantium Claw" has also a very high base critical rate. Unlocks at level 2.
Cyclops (15 CP)
Hawkeye (1 CP)
Invisible Woman (15 CP)
Iron Fist (15 CP)
Phoenix (48 CP)
Sif (23 CP)
Spider-Man (90 CP)
Thor (90 CP)
Heroes with decent critical rates that needs some Iso-8 items to get very high crit rates.
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